ISO/TS TECHNICAL SPECIFICATION 17182 First edition 2014-12-15 Soil quality - Determination of some selected phenols and chlorophenols Gas chromatographic method with mass spectrometric detection Qualité du sol - Dosage de quelques phénols et chlorophénols sélectionnés - Méthode par chromatographie en phase gazeuse avec détection par spectrométrie de masse Reference number IS0/TS 17182:2014(E) LSO @IS0 2014 I without license from IHS IS0/TS 17182:2014(E) COPYRIGHTPROTECTEDDOCUMENT @ISO2014 All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form written permission. Permission can be requested from either ISO at the address below or ISO's member body in the country of the requester. ISO copyright office Case postale 56 : CH-1211 Geneva 20 Tel. + 41 22 749 01 11 Fax + 41 22 749 09 47 E-mail [email protected] Web www.iso.org Published in Switzerland @ IS0 2014 - All rights reserved No reproductic NotforResale, 01/23/2015 11:25:03MST IS0/TS 17182:2014(E) Contents Page Foreword ..iv 1 Scope 2 Normative references ..3 3 Principle 4 Interferences .3 4.1 Interference with sampling and extraction .3 4.2 Interference with GC-MS determination ..4 5 Reagents ..4 5.1 Products used in their commercially available form .4 5.2 Aqueous solutions .4 5.3 Standard solutions of phenols .5 6 Apparatus and equipment ..5 7 Sampling. .6 8 Procedure. .6 8.1 Test portion. . 6 8.2 Dry matter content. .6 8.3 Blank sample .6 8.4 Standard sample 6 8.5 Extraction .6 8.6 Acetylation 7 8.7 Gas chromatographic analysis .7 8.8 Calibration .7 9 Calculation .8 9.1 Calculation of the content of substance i in the extract. .8 9.2 Calculation of the content of selected phenol soil sample per dry matter (mg/kg drymatter) .9 10 Test report .9 Annex A (informative) Typical concentrations of the standard solutions ..10 Annex B (informative) Example of gas chromatographic conditions .11 Bibliography .15 iii Stal se with ISi ithout license from IHS 25:03MS